1: With carbon tetrafluoride; hydrogen fluoride in dichloromethane T=60°C; 24 h; 2: With water; sodium hydrogencarbonate in dichloromethane T=20°C;

copper in dimethyl sulfoxide T=60°C; 6 h;

1.1: isopropylmagnesium chloride lithium chloride complex / tetrahydrofuran / 3.78 h / -29 - -20 °C / Inert atmosphere 1.2: 19.25 h / -53 - 20 °C / Inert atmosphere 1.3: 0.62 h / 10 °C 2.1: [bis(2-methoxyethyl)amino]-sulfur trifluoride / dichloromethane / 0.75 h / 20 °C / Inert atmosphere 2.2: 20 °C 2.3: 2.5 h / 10 - 15 °C View Scheme

hydrazine in ethanol T=20°C; 0.166667 h;