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乙二醇
甲醛
63148-62-9
MDI
丁酮
二甲基亚砜
碳酸氢钠
471-34-1
943611-15-2
合成路线
(共 5 条)
1120-90-7
3-碘吡啶
+
943611-15-2
→
反应条件
1008-88-4
3-苯基吡啶
反应条件
1: 1-{3-[dibutyl(phenyl)stannyl]propyl}-3-methyl-1H-imidazolium iodide With bis(dibenzylideneacetone)-palladium(0) T=35°C; Stille coupling; 0.25 h; Inert atmosphereneat (no solvent); 2: 3-iodo-pyridine T=35°C; Stille coupling; 96 h; Inert atmosphereneat (no solvent);
参考文献
Pham, Phuoc Dien; Vitz, Juergen; Chamignon, Cecile; Martel, Arnaud; Legoupy, Stephanie
European Journal of Organic Chemistry, 2009 , # 19 p. 3249 - 3257
1120-90-7
3-碘吡啶
+
943611-15-2
→
反应条件
1008-88-4
3-苯基吡啶
+
92-52-4
联苯
反应条件
1: 1-{3-[dibutyl(phenyl)stannyl]propyl}-3-methyl-1H-imidazolium iodide With tris(dibenzylideneacetone)dipalladium(0) chloroform complex T=35°C; Stille coupling; 0.25 h; Inert atmosphereneat (no solvent); 2: 3-iodo-pyridine T=35°C; Stille coupling; 72 h; Inert atmosphereneat (no solvent);
参考文献
European Journal of Organic Chemistry, , # 19 p. 3249 - 3257
943611-15-2
+
610-97-9
2-碘苯甲酸甲酯
→
反应条件
92-52-4
联苯
+
16605-99-5
甲基2-联苯羧酸酯
反应条件
1: 1-{3-[dibutyl(phenyl)stannyl]propyl}-3-methyl-1H-imidazolium iodide With tris(dibenzylideneacetone)dipalladium(0) chloroform complex T=35°C; Stille coupling; 0.25 h; Inert atmosphereneat (no solvent); 2: methyl 2-iodobenzoate T=35°C; Stille coupling; 24 h; Inert atmosphereneat (no solvent);
参考文献
European Journal of Organic Chemistry, , # 19 p. 3249 - 3257
624-31-7
4-碘甲苯
+
943611-15-2
→
反应条件
92-52-4
联苯
+
644-08-6
4-甲基联苯
反应条件
1: 1-{3-[dibutyl(phenyl)stannyl]propyl}-3-methyl-1H-imidazolium iodide With tris(dibenzylideneacetone)dipalladium(0) chloroform complex T=35°C; Stille coupling; 0.25 h; Inert atmosphereneat (no solvent); 2: 1-(iodo)-4-methylbenzene T=35°C; Stille coupling; 96 h; Inert atmosphereneat (no solvent);
参考文献
European Journal of Organic Chemistry, , # 19 p. 3249 - 3257
35779-04-5
4-叔丁基碘苯
+
943611-15-2
→
反应条件
92-52-4
联苯
+
1625-92-9
4-叔丁基联苯
反应条件
1: 1-{3-[dibutyl(phenyl)stannyl]propyl}-3-methyl-1H-imidazolium iodide With tris(dibenzylideneacetone)dipalladium(0) chloroform complex T=35°C; Stille coupling; 0.25 h; Inert atmosphereneat (no solvent); 2: 1-tert-butyl-4-iodobenzene T=35°C; Stille coupling; 120 h; Inert atmosphereneat (no solvent);
参考文献
Pham, Phuoc Dien; Vitz, Juergen; Chamignon, Cecile; Martel, Arnaud; Legoupy, Stephanie
European Journal of Organic Chemistry, 2009 , # 19 p. 3249 - 3257