3,5-二甲氧羰基苯硼酸频哪醇酯合成路线 （共 12 条）
反应条件
1: PdCl2(dppf); CsF / dimethylformamide; H2O / 12 h / 80 °C 2: 89 percent / NaOH / tetrahydrofuran; H2O / 1 h / Heating View Scheme
参考文献
Mazik, Monika; Koenig, Alexander
Journal of Organic Chemistry, 2006 , vol. 71, # 20 p. 7854 - 7857
反应条件
hydrogenchloride; sodium periodate in tetrahydrofuran; water T=25°C; 17.5 h;
参考文献
Babu Kumar, Arun; Anderson, Jordan Micheal; Manetsch, Roman
Organic and Biomolecular Chemistry, 2011 , vol. 9, # 18 p. 6284 - 6292
反应条件
potassium acetate; palladium diacetate in N,N-dimethyl-formamide
T=90°C; 12 h; Schlenk techniqueInert atmosphere;
参考文献
Park, Jinhee; Wang, Zhiyong U.; Sun, Lin-Bing; Chen, Ying-Pin; Zhou, Hong-Cai
Journal of the American Chemical Society, 2012 , vol. 134, # 49 p. 20110 - 20116
反应条件
tris-(dibenzylideneacetone)dipalladium(0); BI-DIME; potassium acetate in N,N-dimethyl acetamide
T=100°C; Miyaura borylation; 12 h; Inert atmosphere;
参考文献
Tang, Wenjun; Keshipeddy, Santosh; Zhang, Yongda; Wei, Xudong; Savoie, Jolaine; Patel, Nitinchandra D.; Yee, Nathan K.; Senanayake, Chris H.
Organic Letters, 2011 , vol. 13, # 6 p. 1366 - 1369
反应条件
TEA; (1,1'-bis(diphenylphosphino)ferrocene)palladium(II) dichloride in acetonitrile
T=85°C; 5 h;
参考文献
Muthiah, Chinnasamy; Taniguchi, Masahiko; Kim, Han-Je; Schmidt, Izabela; Kee, Hooi Ling; Holten, Dewey; Bocian, David F.; Lindsey, Jonathan S.
Photochemistry and Photobiology, 2007 , vol. 83, # 6 p. 1513 - 1528
反应条件
1: 49 percent / sodium nitrite; aq. HCl; KI / H2O; toluene / 13 h
2: potassium acetate; PdCl2(dppf) / dimethylformamide / 2 h / 80 °C
View Scheme
参考文献
Mazik, Monika; Koenig, Alexander
European Journal of Organic Chemistry, 2007 , # 20 p. 3271 - 3276
反应条件
dichloro(1,1'-bis(diphenylphosphanyl)ferrocene)palladium(II) dichloromethane adduct; potassium acetate in 1,4-dioxane
15 h; Inert atmosphereSchlenk techniqueReflux;
参考文献
Peng, Yang; Krungleviciute, Vaiva; Eryazici, Ibrahim; Hupp, Joseph T.; Farha, Omar K.; Yildirim, Taner
Journal of the American Chemical Society, 2013 , vol. 135, # 32 p. 11887 - 11894
反应条件
tert.-butylnitrite in acetonitrile
T=80°C; 2 h;
参考文献
Qiu, Di; Jin, Liang; Zheng, Zhitong; Meng, He; Mo, Fanyang; Wang, Xi; Zhang, Yan; Wang, Jianbo
Journal of Organic Chemistry, 2013 , vol. 78, # 5 p. 1923 - 1933
反应条件
[Ir2(OMe)2(1,5-cyclooctadiene)2]; dtbpy in tetrahydrofuran
T=80°C; 18 h; Inert atmosphere; regioselective reaction;
参考文献
Litvinas, Nichole D.; Fier, Patrick S.; Hartwig, John F.
Angewandte Chemie - International Edition, 2012 , vol. 51, # 2 p. 536 - 539
反应条件
1.1: sulfuric acid / 24 h / |Reflux; |Solvolysis
2.1: sodium nitrite; hydrogenchloride / water / -5 °C
2.2: 13 h / -5 °C / |Reflux
3.1: potassium acetate; (1,1'-bis(diphenylphosphino)ferrocene)palladium(II) dichloride / N,N-dimethyl-formamide / 2 h / 80 °C
View Scheme
参考文献
Sukul, Pradip K.; Malik, Sudip
RSC Advances, 2013 , vol. 3, # 6 p. 1902 - 1915
