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乙二醇
甲醛
63148-62-9
MDI
丁酮
二甲基亚砜
碳酸氢钠
471-34-1
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乙二醇
甲醛
63148-62-9
MDI
丁酮
二甲基亚砜
碳酸氢钠
471-34-1
94451-06-6
合成路线
(共 15 条)
94451-06-6
→
反应条件
2381-87-5
4-甲基-5,6-二氢吡喃-2-酮
反应条件
1: 91 percent / Me2S / tetrahydrofuran; diethyl ether / 0.5 h / -25 - -17 °C 2: mCPBA / CH2Cl2 / -15 °C 3: 72 percent / pyridine / benzene / Heating View Scheme
参考文献
Kato, Michiharu; Ouchi, Akihiko; Yoshikoshi, Akira
Bulletin of the Chemical Society of Japan, 1991 , vol. 64, # 5 p. 1479 - 1486
94451-06-6
→
反应条件
73978-11-7
反应条件
1: 91 percent / Me2S / tetrahydrofuran; diethyl ether / 0.5 h / -25 - -17 °C 2: mCPBA / CH2Cl2 / -15 °C 3: 18 percent / (CF3CO)2O / -15 deg C -> r.t., 2-3 d View Scheme
参考文献
Kato, Michiharu; Ouchi, Akihiko; Yoshikoshi, Akira
Bulletin of the Chemical Society of Japan, 1991 , vol. 64, # 5 p. 1479 - 1486
94451-06-6
→
反应条件
88806-73-9
反应条件
1: 82 percent / diethyl ether; tetrahydrofuran / 7 h / -45 - 8 °C 2: mCPBA / CH2Cl2 / -15 °C 3: 73 percent / pyridine / benzene / Heating 4: 51 percent / Me2S / diethyl ether / 0.42 h / -30 °C View Scheme
参考文献
Kato, Michiharu; Ouchi, Akihiko; Yoshikoshi, Akira
Bulletin of the Chemical Society of Japan, 1991 , vol. 64, # 5 p. 1479 - 1486
94451-06-6
→
反应条件
89030-26-2
反应条件
1: 80 percent / diethyl ether / 0.5 h / -20 - -17 °C 2: mCPBA / CH2Cl2 / -15 °C 3: 79 percent / pyridine / benzene / Heating View Scheme
参考文献
Kato, Michiharu; Ouchi, Akihiko; Yoshikoshi, Akira
Bulletin of the Chemical Society of Japan, 1991 , vol. 64, # 5 p. 1479 - 1486
94451-06-6
→
反应条件
89030-27-3
反应条件
1: 82 percent / diethyl ether; tetrahydrofuran / 7 h / -45 - 8 °C 2: mCPBA / CH2Cl2 / -15 °C 3: 73 percent / pyridine / benzene / Heating View Scheme
参考文献
Kato, Michiharu; Ouchi, Akihiko; Yoshikoshi, Akira
Bulletin of the Chemical Society of Japan, 1991 , vol. 64, # 5 p. 1479 - 1486
94451-06-6
→
反应条件
89030-28-4
反应条件
1: 73 percent / diethyl ether; tetrahydrofuran / 1.5 h / 0 °C 2: mCPBA / CH2Cl2 / -15 °C 3: 80 percent / pyridine / benzene / Heating View Scheme
参考文献
Kato, Michiharu; Ouchi, Akihiko; Yoshikoshi, Akira
Bulletin of the Chemical Society of Japan, 1991 , vol. 64, # 5 p. 1479 - 1486
94451-06-6
→
反应条件
89030-29-5
反应条件
1: 91 percent / Me2S / tetrahydrofuran; diethyl ether / 0.5 h / -25 - -17 °C 2: mCPBA / CH2Cl2 / -15 °C 3: 52 percent / (CF3CO)2O / -15 deg C -> r.t., 2-3 d View Scheme
参考文献
Kato, Michiharu; Ouchi, Akihiko; Yoshikoshi, Akira
Bulletin of the Chemical Society of Japan, 1991 , vol. 64, # 5 p. 1479 - 1486
94451-06-6
→
反应条件
89030-30-8
反应条件
1: 80 percent / diethyl ether / 0.5 h / -20 - -17 °C 2: mCPBA / CH2Cl2 / -15 °C 3: 49 percent / (CF3CO)2O / -15 deg C -> r.t., 2-3 d View Scheme
参考文献
Kato, Michiharu; Ouchi, Akihiko; Yoshikoshi, Akira
Bulletin of the Chemical Society of Japan, 1991 , vol. 64, # 5 p. 1479 - 1486
94451-06-6
→
反应条件
89030-31-9
反应条件
1: 82 percent / diethyl ether; tetrahydrofuran / 7 h / -45 - 8 °C 2: mCPBA / CH2Cl2 / -15 °C 3: 10 percent / (CF3CO)2O / -15 deg C -> r.t., 2-3 d View Scheme
参考文献
Kato, Michiharu; Ouchi, Akihiko; Yoshikoshi, Akira
Bulletin of the Chemical Society of Japan, 1991 , vol. 64, # 5 p. 1479 - 1486
94451-06-6
→
反应条件
89030-32-0
反应条件
1: 80 percent / diethyl ether / 0.5 h / -20 - -17 °C 2: 76 percent / W-4 Raney nickel / ethanol / Ambient temperature; 1-3 h View Scheme
参考文献
Kato, Michiharu; Ouchi, Akihiko; Yoshikoshi, Akira
Bulletin of the Chemical Society of Japan, 1991 , vol. 64, # 5 p. 1479 - 1486
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