2-溴-5-(5-噻吩-2-基噻吩-2-基)噻吩合成路线 (共 5 条)
反应条件
in acetonitrile T=26.9°C; Rate constant;
参考文献
Journal of the American Chemical Society, , vol. 112, # 7 p. 2694 - 2701
反应条件
potassium fluoride; 4,4,5,5-tetramethyl-1,3,2-dioxaborolan-2-yl-4',4',5',5'-tetramethyl-1,3,2-dioxaborolane; (1,1'-bis(diphenylphosphino)ferrocene)palladium(II) dichloride in methanol; toluene T=70°C; Suzuki coupling; 0.166667 h; microwave irradiation;
参考文献
Melucci; Barbarella; Zambianchi; Di Pietro; Bongini
Journal of Organic Chemistry, 2004 , vol. 69, # 14 p. 4821 - 4828
反应条件
[1,3-bis(diphenylphosphino) propane] dichloronickel(II) in tetrahydrofuran; diethyl ether
参考文献
Martinez, F.; Voelkel, R.; Naegele, D.; Naarmann, H.
Molecular Crystals and Liquid Crystals (1969-1991), 1989 , vol. 167, p. 227 - 232
反应条件
1: copper(l) iodide; bis-triphenylphosphine-palladium(II) chloride; triethylamine / tetrahydrofuran / 12 h / 65 °C / Inert atmosphere
2: methanol; potassium carbonate / tetrahydrofuran / 1 h / 20 °C
View Scheme
参考文献
Hinkens, Diane M.; Chen, Qiliang; Siddiki, Mahbube Khoda; Gosztola, David; Tapsak, Mark A.; Qiao, Qiquan; Jeffries-El, Malika; Darling, Seth B.
Polymer (United Kingdom), 2013 , vol. 54, # 14 p. 3510 - 3520
反应条件
1: 5-bromo-lt;2,2',5',2''gt;-terthiophene With magnesium; ethylene dibromide in tetrahydrofuran
T=20°C; 1 h; sonication;
2: chloro-diphenylphosphine in diethyl ether; hexane
T=20°C; 1 h; Further stages.;
参考文献
Field, John S.; Haines, Raymond J.; Lakoba, Elena I.; Sosabowski, M. Hal
Journal of the Chemical Society. Perkin Transactions 1, 2001 , # 24 p. 3352 - 3360