lithium aluminium tetrahydride in diethyl ether T=20°C; 0.0833333 h; var. (E)-1-aryl-3-halopropenes, (E)-1-aryl-3-halobutanes, (9-anthryl)arylmethyl halides; other reductors; other solvents; Product distributionMechanism;

potassium carbonate; 3,4,5-trimethoxyphenylboronic acid; [Ru(cyclopentadienyl)(MeCN)3]PF6 in acetonitrile T=20°C; 16 h;

lithium aluminium tetrahydride in diethyl ether T=20°C; 0.0833333 h; var. (E)-1-aryl-3-halopropenes, (E)-1-aryl-3-halobutanes, (9-anthryl)arylmethyl halides; other reductors; other solvents; Product distributionMechanism;

1: 2-(4-methoxyphenyl)-4,4,5,5-tetramethyl-1,3,2-dioxaborolane With potassium tert-butylate in 1,4-dioxane 0.166667 h; Inert atmosphereGlove box; 2: With IMesCuOtBu in 1,4-dioxane T=20°C; 0.166667 h; Inert atmosphereGlove box; 3: (E)-1-(3-chloroprop-1-en-1-yl)-4-methoxybenzene in 1,4-dioxane T=45°C; 24 h; Inert atmosphereGlove box; regioselective reaction;

potassium carbonate

in 2,2,2-trifluoroethanol T=22°C; Inert atmosphereFlash photolysis;