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乙二醇
甲醛
63148-62-9
MDI
丁酮
二甲基亚砜
碳酸氢钠
471-34-1
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乙二醇
甲醛
63148-62-9
MDI
丁酮
二甲基亚砜
碳酸氢钠
471-34-1
94922-11-9
合成路线
(共 16 条)
119952-29-3
→
反应条件
94922-11-9
反应条件
triethylsilane; caesium carbonate; tetrakis(triphenylphosphine) palladium(0) in N,N-dimethyl-formamide T=80°C; 4 h;
参考文献
Oh, Chang Ho; Park, Su Jin
Tetrahedron Letters, 2003 , vol. 44, # 19 p. 3785 - 3787
92105-14-1
→
反应条件
94922-11-9
反应条件
potassium carbonate; Pd(OAc)2*PPh3 in acetonitrile 3.5 h; Heating;
参考文献
Grigg, Ronald; Stevenson, Paul; Worakun, Tanachat
Tetrahedron, 1988 , vol. 44, # 7 p. 2049 - 2054
101268-55-7
2-烯丙基-2-(2-丙炔基)丙二酸二乙酯
→
反应条件
94922-11-9
反应条件
Grubb's 2nd generation catalyst; N,N-dimethyl-formamide in toluene 0.333333 h; Inert atmosphereReflux;
参考文献
Mallagaray, Alvaro; Mohammadiannejad-Abbasabadi, Kazem; Medina, Sandra; Dominguez, Gema; Perez-Castells, Javier
Organic and Biomolecular Chemistry, 2012 , vol. 10, # 33 p. 6665 - 6672
101268-55-7
2-烯丙基-2-(2-丙炔基)丙二酸二乙酯
→
反应条件
94922-11-9
+
93638-77-8
反应条件
piperidine; formic acid; palladium diacetate; triphenylphosphine in acetonitrile 0.0166667 h; Heating;
参考文献
Grigg, Ronald; Stevenson, Paul; Worakun, Tanachat
Tetrahedron, 1988 , vol. 44, # 15 p. 4967 - 4972
118453-14-8
+
86595-37-1
2-叔丁基-E-乙烯基硼酸
→
反应条件
反应条件
tetrakis(triphenylphosphine) palladium(0); caesium carbonate in ethanol T=70°C; 2 h;
参考文献
Oh, Chang Ho; Sung, Hye Rhyan; Park, Su Jin; Ahn, Kyo Han
Journal of Organic Chemistry, 2002 , vol. 67, # 20 p. 7155 - 7157
118453-14-8
→
反应条件
94922-11-9
反应条件
triphenylphosphine; silver carbonate; palladium diacetate in acetonitrile T=85°C; Heck reaction; 0.75 h;
参考文献
Bhat, Laxminarayan; Steinig, Arno G.; Appelbe, Ruth; De Meijere, Armin
European Journal of Organic Chemistry, 2001 , # 9 p. 1673 - 1680
113281-34-8
→
反应条件
94922-11-9
+
93638-77-8
+
113281-28-0
+
119952-31-7
反应条件
piperidine; formic acid; triphenylphosphine; palladium diacetate in acetonitrile T=80°C; Yield given. Yields of byproduct given;
参考文献
Burns, Barry; Grigg, Ronald; Sridharan, Visuvanathar; Worakun, Tanachat
Tetrahedron Letters, 1988 , vol. 29, # 34 p. 4325 - 4328
201230-82-2
+
118453-14-8
→
反应条件
94922-11-9
+
143208-12-2
+
197155-69-4
反应条件
tri-tert-butyl phosphine; sodium acetate; tris(dibenzylideneacetone)dipalladium(0) chloroform complex in N,N-dimethyl-formamide T=80°C; P=1520.1 Torr; 24 h; Product distribution; Further Variations:ReagentsPressures;
参考文献
Aggarwal, Varinder K.; Davies, Paul W.; Moss, William O.
Chemical Communications, 2002 , # 9 p. 972 - 973
80356-22-5
+
105-53-3
丙二酸二乙酯
→
反应条件
94922-11-9
反应条件
potassium hydroxide; tetrabutyl-ammonium chloride in methanol; diethyl ether; water 10 h;
参考文献
Mueller, Paul; Miao, Zhongshan
Helvetica Chimica Acta, 1994 , vol. 77, # 7 p. 1826 - 1836
118453-14-8
+
98-80-6
苯硼酸
→
反应条件
94922-11-9
反应条件
tetrakis(triphenylphosphine) palladium(0); potassium carbonate in ethanol T=60°C; Heck reaction; 4 h;
参考文献
Oh, Chang Ho; Sung, Hye Rhyan; Park, Su Jin; Ahn, Kyo Han
Journal of Organic Chemistry, 2002 , vol. 67, # 20 p. 7155 - 7157
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