1: CH2-indene With n-butyllithium in diethyl ether
T=0°C;
2: i-propyl-halide in diethyl ether
T=0°C;
参考文献
Galin, F. Z.; Ignatyuk, V. K.; Lakeev, S. N.; Tolstikov, G. A.
Journal of Organic Chemistry USSR (English Translation), 1987 , vol. 23, # 6 p. 1214
Zhurnal Organicheskoi Khimii, 1987 , vol. 23, # 6 p. 1341 - 1342
1: With [RhCl(η2:η2-cycloocta-1,5-diene)]2; N,N,N',N'-tetramethyl-1,4-butanediamine in acetonitrile
P=10351 Torr; Autoclave;
2: With hydrogen in acetonitrile
T=60°C; P=10351 Torr; 21 h; Autoclave;
参考文献
Cheung, Lawrence L. W.; Vasapollo, Giuseppe; Alper, Howard
Advanced Synthesis and Catalysis, 2012 , vol. 354, # 10 p. 2019 - 2022
bimacrocyclic concave 1,10-phenanthroline ligand; copper trifluoromethanesulfonate in 1,2-dichloro-ethane
T=20°C; Cycloaddition; Cyclopropanation; Title compound not separated from byproducts;
1,10-phenanthroline-bridged calix[6]arene; copper trifluoromethanesulfonate in 1,2-dichloro-ethane
T=20°C; Cycloaddition; Cyclopropanation; Title compound not separated from byproducts;
