反应条件
1: 1.) EtMgBr / 1.) Et2O, 2 h, reflux; 2.) Et2O, 30 min 2: 1.) BH3*SMe2, 2.) CH3OH / 1.) THF, 0 deg C, 2 h; r.t., 2 h, 2.) THF, 1 h, reflux 3: 80 percent / O3/O2 / ethyl acetate / 14 h 4: 67 percent / 5M HCl / ethanol / 3 h / Heating 5: 1.) NaNO2, 10M HCl, 2.) NaN3 / 1.) H2O, 0 deg C, 30 min, 2.) H2O, 10 min 6: 75 percent / NH2NH2*H2O, CH3COOH / ethanol / 15 h / Heating View Scheme
参考文献
Clark, Brian J.; Grayshan, Roger
Journal of Chemical Research, Miniprint, 1981 , # 10 p. 3786 - 3795
