Goossens, Hans D.; Lambrechts, Hans J. A.; Cerfontain, Hans; Wit, Peter de
Recueil des Travaux Chimiques des Pays-Bas, 1988 , vol. 107, # 6 p. 426 - 430
sulfuric acid T=25°C; the sulphonation of various aromatic ethers and alcohols at variation of H2SO4 concentration; Rate constantProduct distributionMechanism;
参考文献
Cerfontain, Hans; Lambrechts, Hans J. A.; Schaasberg-Nienhuis, Zwaan R. H.; Coombes, Robert G.; Hadjigeorgiou, Panicos; Tucker, Geoffrey
Journal of the Chemical Society, Perkin Transactions 2: Physical Organic Chemistry (1972-1999), 1985 , p. 659 - 668
Hantke
Chemische Berichte, 1887 , vol. 20, p. 3210
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Engelhard; Latschinow
Zeitschrift fuer Chemie, 1869 , p. 621
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Claus; Jackson
Journal fuer Praktische Chemie (Leipzig), 1888 , vol. <2> 38, p. 328
1.1: sodium hydroxide / water / 6.5 h / 60 °C 2.1: nitric acid / 1.67 h / -15 °C 3.1: sodium hydroxide / water / 0.5 h 3.2: 6.25 h / 0 - 70 °C 4.1: dihydrogen peroxide / methanol; water / 4 h / 5 - 10 °C 5.1: potassium carbonate / N,N-dimethyl-formamide / 0.5 h 5.2: 3.5 h / 5 - 20 °C 6.1: ammonia / ethanol; water / 6 h / 90 °C / Autoclave 7.1: sodium dithionite / methanol; water / 12 h / Reflux 8.1: sodium hydride / N,N-dimethyl-formamide; mineral oil / 1 h / 0 °C 8.2: 12 h / 0 - 20 °C 9.1: sodium hydroxide / methanol; water / 3 h / Reflux 9.2: pH 5 View Scheme
1: ortho-cresol With tris-(dibenzylideneacetone)dipalladium(0); sodium hydroxide; di-tert-butyl(2′,4′,6′-triisopropylbiphenyl-2-yl)phosphine in 1,4-dioxane; polyethylene glycol; water T=80°C; 1 h; 2: 1-bromo-3,5-dimethyl-benzene in 1,4-dioxane; polyethylene glycol; water T=80°C;
参考文献
Journal of Physical Chemistry A, , vol. 114, # 11 p. 3932 - 3938
