sulfuric acid; nitric acid
T=8 - 10°C; man trennt die Isomeren durch aufeinanderfolgende fraktionierte Krystallisation aus konz. Schwefelsaeure und Alkohol;
参考文献
Morgan; Drew
Journal of the Chemical Society, 1920 , vol. 117, p. 789
1: 9-bromo-anthracene With magnesium in tetrahydrofuran
2: ortho-chlorotoluene With tris(dibenzylideneacetone)dipalladium (0) in tetrahydrofuran
T=25°C; Kumada-Corriu cross-coupling; 24 h; Further stages.;
参考文献
Wolf, Christian; Xu, Hanhui
Journal of Organic Chemistry, 2008 , vol. 73, # 1 p. 162 - 167
1: n-butyl-magnesium chloride With zinc(II) chloride in tetrahydrofuran
T=20°C; 0.333333 h;
2: ortho-chlorotoluene With Pd0(tris(tert-butyl)phosphine)2 in tetrahydrofuran; 1-methyl-pyrrolidin-2-one
T=100°C; Negishi reaction; 20 h; Further stages.;
参考文献
Dai; Fu
Journal of the American Chemical Society, 2001 , vol. 123, # 12 p. 2719 - 2724
