1: With tris-(dibenzylideneacetone)dipalladium(0); 4-bromo-phenol; C30H23O2P in tetrahydrofuran T=-78 - 25°C; 2.16667 h; 2: With hydrogenchloride in tetrahydrofuran; water
1: With tris-(dibenzylideneacetone)dipalladium(0); BF4(1-)*C30H35O2P*H(1+) in tetrahydrofuran T=-78 - 25°C; 1.16667 h; 2: With hydrogenchloride in tetrahydrofuran; water
1.1: 84 percent / triethylamine / DMAP / tetrahydrofuran / 0 - 20 °C 2.1: Bu3SnH; α,α'-azobis(isobutyronitrile) / benzene / 7.5 h 2.2: 38 percent / methyllithium / benzene / 12 h / 20 °C View Scheme
参考文献
Manley, David W.; McBurney, Roy T.; Miller, Phillip; Walton, John C.; Mills, Andrew; O'Rourke, Christopher
Journal of Organic Chemistry, 2014 , vol. 79, # 3 p. 1386 - 1398
