1,2,4,5-四甲基苯合成路线 （共 381 条）
反应条件
aluminium trichloride in carbon disulfide 1.) 25 deg C, 1 h; 2.) 50 deg C, 3 h;
参考文献
Andreou et al.
Tetrahedron, 1980 , vol. 36, p. 2101
参考文献
National Distillers and Chemical Corporation
Patent: US4096149 A1, 1978 ;
参考文献
National Distillers and Chemical Corporation
Patent: US4096149 A1, 1978 ;
反应条件
aluminium trichloride Erwaermen mit Natronlauge und Behandeln mit Salzsaeure;
参考文献
Jacobsen
Chemische Berichte, 1889 , vol. 22, p. 1217
反应条件
carbon disulfide; aluminium trichloride durch Verseifen mit NaNO2 in verd. Schwefelsaeure;
参考文献
Gattermann
Chemische Berichte, 1899 , vol. 32, p. 1119
Justus Liebigs Annalen der Chemie, 1888 , vol. 244, p. 55
反应条件
in acetonitrile Irradiationvarious reaction conditions; Product distributionMechanism;
参考文献
Masnovi, J. M.; Sankararaman, S.; Kochi, J. K.
Journal of the American Chemical Society, 1989 , vol. 111, # 6 p. 2263 - 2276
反应条件
potassium permanganate; N-hexadecyl-N,N,N-trimethylammonium bromide in water T=90°C; 4.5 h;
参考文献
Journal of Organic Chemistry USSR (English Translation), , vol. 16, # 4 p. 612 - 615
Zhurnal Organicheskoi Khimii, , vol. 16, # 4 p. 698 - 702
反应条件
oxygen; zirconium (IV) sulphate; anhydrous cobalt diacetate; Manganese (II) acetate; 2,6-dihydroxypyromellitimide in acetic acid T=120°C; P=6000.6 Torr; 6 h; Product distribution / selectivity;
参考文献
US2011/71314 A1, ;
Page/Page column 15 ;
反应条件
1: With oxygen; acetic acid; anhydrous cobalt diacetate; Manganese (II) acetate; 2,6-dihydroxypyromellitimide in water T=120°C; P=30003 Torr; 2 h; 2: With acetic anhydride in water T=120 - 150°C; P=3750.38 - 30003 Torr; 4 h; Product distribution / selectivity;
参考文献
EP1862442 A1, ;
Page/Page column 17 ;
反应条件
oxygen; zirconium (IV) sulphate; anhydrous cobalt diacetate; Manganese (II) acetate; 2,6-dihydroxypyromellitimide in acetic acid T=80 - 120°C; P=15001.5 Torr; 2 h; Product distribution / selectivity;
参考文献
US2011/71314 A1, ;
Page/Page column 13 ;
