二螺[5,1,5,1]十四烷-7,14-二酮合成路线 （共 19 条）
反应条件
T=190 - 210°C; P=0.1 - 0.2 Torr; 0.25 h;
参考文献
Letcher, Roy M.; Choi, Michael C.K.; Acheson, R.Morrin
Journal of the Chemical Society, Perkin Transactions 1: Organic and Bio-Organic Chemistry (1972-1999), 1983 , # 3 p. 515 - 526
反应条件
T=220°C; P=0.1 Torr;
参考文献
Letcher, Roy M.; Choi, Michael C. K.; Acheson, R. Morrin
Journal of Chemical Research, Miniprint, 1985 , # 5 p. 1634 - 1672
反应条件
n-butyllithium; chloro-trimethyl-silane; triethylamine
1.) THF, hexane, -78 deg C, 0,5 h, 2.) 25 deg C, 2 h; Yield given. Multistep reaction. Yields of byproduct given;
参考文献
Baigrie, Lynn M.; Lenoir, Dieter; Seikaly, Hani R.; Tidwell, Thomas T.
Journal of Organic Chemistry, 1985 , vol. 50, # 12 p. 2105 - 2109
反应条件
triphenyl phosphite; ozone
1.) -80 deg C, methylene chloride 2.) room temperature, 2 h; Yield given. Multistep reaction;
参考文献
Sundari, B.; Ramamurthy, V.
Indian Journal of Chemistry, Section B: Organic Chemistry Including Medicinal Chemistry, 1984 , vol. 23, # 6 p. 498 - 501
反应条件
triethylamine
1.) THF, hexane, -78 deg C, 0,5 h, 2.) 25 deg, 2 h; Yield given. Multistep reaction. Yields of byproduct given;
参考文献
Baigrie, Lynn M.; Lenoir, Dieter; Seikaly, Hani R.; Tidwell, Thomas T.
Journal of Organic Chemistry, 1985 , vol. 50, # 12 p. 2105 - 2109
反应条件
triethylamine
1.) THF, -78 deg C, 0.5 h, 2.) 25 deg C, 2 h; Yield given. Multistep reaction. Title compound not separated from byproducts;
参考文献
Baigrie, Lynn M.; Lenoir, Dieter; Seikaly, Hani R.; Tidwell, Thomas T.
Journal of Organic Chemistry, 1985 , vol. 50, # 12 p. 2105 - 2109
反应条件
in benzene
0.5 h; Irradiation;
参考文献
Kuzmanich, Gregory; Spaenig, Fabian; Tsai, Chao-Kuan; Um, Joann M.; Hoekstra, Ryan M.; Houk; Guldi, Dirk M.; Garcia-Garibay, Miguel A.
Journal of the American Chemical Society, 2011 , vol. 133, # 8 p. 2342 - 2345
反应条件
dichloromethane
Irradiation.UV-Licht;
参考文献
Kuzmanich, Gregory; Garcia-Garibay, Miguel A.
Journal of Physical Organic Chemistry, 2011 , vol. 24, # 10 p. 883 - 888
反应条件
T=-70°C; Irradiation;
参考文献
Kimura,K. et al.
Bulletin of the Chemical Society of Japan, 1976 , vol. 49, # 3 p. 741 - 745
