trans-[Pt(μ-Cl)Cl(C2H4)]2 in 1,4-dioxane T=90°C; P=2585.74 Torr;

1: [2-((Z)-1-Benzenesulfonyl-2-phenyl-vinyl)-phenyl]-methyl-amine With lithium hexamethyldisilazane in tetrahydrofuran T=0 - 20°C; 2: ethyl iodide in tetrahydrofuran T=20°C; 1 h;

borane in tetrahydrofuran

1.1: 88 percent / LiAlH4 / tetrahydrofuran / 3 h / 20 °C 2.1: 76 percent / tetrahydrofuran / Heating 3.1: 84 percent / Ph3P; N-bromosuccinimide / tetrahydrofuran / 2 h / 20 °C 4.1: 88 percent / dimethylformamide / 12 h / 80 °C 5.1: LHMDS / tetrahydrofuran / 0.5 h / -78 °C 5.2: tetrahydrofuran / 1 h / -78 °C 6.1: tetrahydrofuran / 2 h / 20 °C 7.1: 1.33 g / t-BuOK / tetrahydrofuran / 1 h / 0 °C 8.1: 1.06 g / aq. HCl / ethyl acetate / 2 h / 20 °C 9.1: LHMDS / tetrahydrofuran / 0 - 20 °C 9.2: 86 percent / tetrahydrofuran / 1 h / 20 °C View Scheme

in diethyl ether Irradiationdifferent solvents; MechanismQuantum yieldProduct distribution;