1-(3-甲基苯基)-2-苯乙酮合成路线 （共 15 条）
反应条件
Iron(II,III) oxide nanopowder
T=200 - 250°C; dowtherm AInert atmosphere;
参考文献
Cognis IP Management GmbH
Patent: EP2468708 A1, 2012 ;
Location in patent: Page/Page column 3-4 ;
反应条件
1,4-diaza-bicyclo[2.2.2]octane; water; oxygen in acetonitrile
T=80°C; P=760.051 Torr; 12 h; chemoselective reaction;
参考文献
Su, Yijin; Sun, Xiang; Wu, Guolin; Jiao, Ning
Angewandte Chemie - International Edition, 2013 , vol. 52, # 37 p. 9808 - 9812
Angew. Chem., 2013 , p. 9990 - 9994
反应条件
bis-triphenylphosphine-palladium(II) chloride; triethylamine in tetrahydrofuran
T=80°C; 3 h; Schlenk tubeInert atmosphere;
参考文献
Rao, Maddali L.N.; Giri, Somnath; Jadhav, Deepak N.
Tetrahedron Letters, 2009 , vol. 50, # 45 p. 6133 - 6138
反应条件
tris-(dibenzylideneacetone)dipalladium(0); bis[2-(diphenylphosphino)phenyl] ether; sodium t-butanolate in tetrahydrofuran
T=70°C; Schlenk techniqueInert atmosphere;
参考文献
Mehta, Vaibhav P.; Garcia-Lopez, Jose-Antonio; Greaney, Michael F.
Angewandte Chemie - International Edition, 2014 , vol. 53, # 6 p. 1529 - 1533
Angew. Chem., 2014 , vol. 126, # 6 p. 1555 - 1559,5
反应条件
Ni(PCy3)2Cl2; sodium t-butanolate in N,N-dimethyl-formamide; toluene
T=100°C; Suzuki-Miyaura coupling; 0.666667 h; Inert atmosphere;
参考文献
Huang, Kun; Li, Gang; Huang, Wei-Ping; Yu, Da-Gang; Shi, Zhang-Jie
Chemical Communications, 2011 , vol. 47, # 25 p. 7224 - 7226
反应条件
palladium diacetate; 1,4-di(diphenylphosphino)-butane; zinc in 1,4-dioxane
T=100°C; Negishi coupling reaction; 3 h; Inert atmosphere;
参考文献
Wu, Xiao-Feng; Schranck, Johannes; Neumann, Helfried; Beller, Matthias
Chemistry - An Asian Journal, 2012 , vol. 7, # 1 p. 40 - 44
反应条件
[rhenium(pentacarbonyl)(bromide)]
2 h; Heating;
参考文献
Kusama, Hiroyuki; Narasaka, Koichi
Bulletin of the Chemical Society of Japan, 1995 , vol. 68, # 8 p. 2379 - 2384
反应条件
1: 87 percent / HCl / methanol
2: 1.) methyltriphenoxyphosphonium iodide; 2.) HCl / 1.) HMPT, 90 deg C, 3 h; 2.) MeOH, reflux
View Scheme
参考文献
Tsuge, Otohiko; Kanemasa, Shuji; Nagahama, Hideki; Tanaka, Junji
Chemistry Letters, 1984 , p. 1803 - 1806
反应条件
1: 82 percent / NaH
2: 87 percent / HCl / methanol
3: 1.) methyltriphenoxyphosphonium iodide; 2.) HCl / 1.) HMPT, 90 deg C, 3 h; 2.) MeOH, reflux
View Scheme
参考文献
Tsuge, Otohiko; Kanemasa, Shuji; Nagahama, Hideki; Tanaka, Junji
Chemistry Letters, 1984 , p. 1803 - 1806
参考文献
Otter; Shriner
Journal of the American Chemical Society, 1951 , vol. 73, p. 887,888
