formic acid; palladium diacetate; bis[2-(diphenylphosphino)phenyl] ether in tetrahydrofuran; dichloromethane T=25 - 105°C; P=3620.13 - 5171.62 Torr; 18.3333 h;

暂无反应条件数据

1.1: 77.7 percent / boron trifluoride diethyl etherate; EtOH; isopropanol / acetonitrile / 24 h / -18.4 °C 2.1: potassium acetate; dibromantin / acetone; H2O / -10 °C 3.1: aq. HCl / CH2Cl2 / 2.5 h / 20 °C 4.1: O3/O2 / CH2Cl2; propan-2-ol / 0.17 h / -55 °C 4.2: dimethylsilfide / CH2Cl2; propan-2-ol / 0.83 h / 20 °C 5.1: 0.865 mg / H2O2; KHCO3 / H2O; methanol / 16 h / 20 °C 6.1: 50.94 g / acetone; H2O / 3 h / 45 °C View Scheme

1: 82 g / AlEt3 / hexane; tetrahydrofuran / 0.5 h / Heating 2: 6.9 g / DIBAH / 1,2-dimethoxy-ethane; hexane / 2 h / 5 °C 3: 6.6 g / aq. CrO3, H2SO4 / acetone / 0.5 h / 5 °C 4: 2.7 g / CH2Cl2; diethyl ether / 0.17 h 5: 71.6 percent / aq. H2O2, (CCl3CO)2O / CH2Cl2 / 1.5 h / below 4 deg C View Scheme