1: With lithium hexamethyldisilazane in tetrahydrofuran; N,N-dimethyl-formamide T=-70 - -15°C; 0.5 h; 2: With N-bromosuccinmide in tetrahydrofuran; N,N-dimethyl-formamide T=-60°C; 0.5 h;

dichloro(1,1'-bis(diphenylphosphanyl)ferrocene)palladium(II) dichloromethane adduct; potassium carbonate; cesium fluoride in 2-methyl tetrahydrofuran; water T=75°C; Suzuki-Miyaura Coupling; 16 h; Inert atmosphere;