1: Z-3-chloro-4,4-dimethyl-2-pentenal With sodium sulfide in DMF (N,N-dimethyl-formamide); water T=20°C; 0.833333 h; 2: bromoacetic acid methyl ester in DMF (N,N-dimethyl-formamide); water T=20°C; 1.5 h; 3: With hydrogenchloride in DMF (N,N-dimethyl-formamide); water 1 h;
diphenylphosphinobenzene-3-sulfonic acid sodium salt; potassium carbonate in methanol
参考文献
O'Brien, Christopher J.; Lavigne, Florie; Coyle, Emma E.; Holohan, Andrew J.; Doonan, Bryan J.
Chemistry - A European Journal, 2013 , vol. 19, # 19 p. 5854 - 5858
THE ROYAL INSTITUTION FOR THE ADVANCEMENT OF LEARNING/McGILL UNIVERSITY; THE HONG KONG POLYTECHNIC UNIVERSITY; CHAN, Tak-Hang; HUO, Congde; HE, Xun
Patent: WO2010/12096 A1, 2010 ;
Location in patent: Page/Page column 17; 26 ;
phosphorous acid diethyl ester; decacarbonyldimanganese (2) T=140°C; 1 h; different concentrations of reagens; Product distributionMechanism;
参考文献
Bulletin of the Academy of Sciences of the USSR, Division of Chemical Science (English Translation), , vol. 38, # 8.2 p. 1749 - 1751
Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, , # 8 p. 1903 - 1905
