2-氯-4,6-二硝基甲苯合成路线 (共 7 条)
反应条件
1: alcoholic tin (II)-chloride; hydrochloric acid View Scheme
参考文献
Morgan; Drew
Journal of the Chemical Society, 1920 , vol. 117, p. 789
反应条件
sulfuric acid; chlorine; silver sulphate
T=85°C; 40 h; Yield given;
参考文献
Segura, Pascual; Bunnett, Joseph F.; Villanova, Laura
Journal of Organic Chemistry, 1985 , vol. 50, # 7 p. 1041 - 1045
反应条件
sulfuric acid; nitric acid
T=40 - 45°C; dann bei 90grad; man trennt die isomeren Verbindungen durch fraktionierte Krystallisation aus konz. Schwefelsaeure;
参考文献
Morgan; Challenor
Journal of the Chemical Society, 1921 , vol. 119, p. 1540
Full Text Show Details
Morgan; Drew
Journal of the Chemical Society, 1920 , vol. 117, p. 789
反应条件
sulfuric acid; nitric acid
T=20°C; dann bei 70-80grad;
参考文献
Morgan; Drew
Journal of the Chemical Society, 1920 , vol. 117, p. 789
Full Text Show Details
Morgan; Jones
Journal of the Chemical Society, 1921 , vol. 119, p. 191
反应条件
sulfuric acid; nitric acid; chlorine
T=90°C; 0.8 h; further reaction times; oleum instead of sulphuric acid; Rate constantMechanismProduct distribution;
参考文献
Melhuish, Martin W.; Moodie, Roy B.
Journal of the Chemical Society, Perkin Transactions 2: Physical Organic Chemistry (1972-1999), 1989 , p. 667 - 674
参考文献
Morgan; Drew
Journal of the Chemical Society, 1920 , vol. 117, p. 789
反应条件
sodium dichromate; sulfuric acid
参考文献
Segura, Pascual; Bunnett, Joseph F.; Villanova, Laura
Journal of Organic Chemistry, 1985 , vol. 50, # 7 p. 1041 - 1045