2,4,6-三叔丁基苯胺合成路线 （共 27 条）
反应条件
1: sodium nitrite; copper (I)-bromide; aqueous hydrogen bromide
2: butyl lithium / anschliessend Behandeln mit CO2
View Scheme
参考文献
Betts; Barclay
Canadian Journal of Chemistry, 1955 , vol. 33, p. 1768,1769
反应条件
1: disulphur dichloride
2: Ph3P, O2 / diethyl ether / -78.1 °C
View Scheme
参考文献
Iwasaki, Fujiko
Acta Crystallographica, Section B: Structural Crystallography and Crystal Chemistry, 1980 , vol. 36, p. 1700 - 1703
反应条件
1: (electrochemical oxidation)
2: diethyl ether
View Scheme
参考文献
Brachi,J.; Rieker,A.
Synthesis, 1977 , p. 708 - 711
反应条件
(C2H5){CH(CH3)2}2N in diethyl ether
byproducts: HF; soln. of the ethyl(isopropyl)amine and a soln. of the 2,4,6-tri-t-butylaniline added dropwise to a soln. of the BF3*OEt2 at 0°C, warmed to room temp., stirred for 2 d; ppt. filtered off, solvent removed in vac., sublimed (0.01 mbar); elem. anal.;
参考文献
Elter, Gernot; Neuhaus, Michael; Meller, Anton; Schmidt-Baese, Dieter
Journal of Organometallic Chemistry, 1990 , vol. 381, # 3 p. 299 - 313
反应条件
n-Butyl nitrite; 2,2,2-trimethylacetic acid in dichloromethane
参考文献
Barclay,L.R.C. et al.
Canadian Journal of Chemistry, 1979 , vol. 57, p. 2172 - 2179
反应条件
acetic anhydride; acetic acid
参考文献
Burgers et al.
Recueil des Travaux Chimiques des Pays-Bas, 1956 , vol. 75, p. 1327,1335
参考文献
Habib, Nargues S.; Rieker, Anton
Zeitschrift fuer Naturforschung, Teil B: Anorganische Chemie, Organische Chemie, 1984 , vol. 39, # 11 p. 1593 - 1597
