1,4,7-三甲基-1,4,7-三氮杂环壬烷合成路线 （共 9 条）
反应条件
1: tri-Ts-1,4,7-triazacyclononane With sulfuric acid in water T=140°C; 6 h; 2: With sodium hydroxide in water Cooling with ice; 3: formaldehyd With formic acid in water T=90°C;
参考文献
US7674866 B2, ;
Page/Page column 17 ;
反应条件
1: With hydrogenchloride; water T=140°C; 6 h; 2: With sodium hydroxide; formaldehyd; formic acid in water T=0 - 90°C; Further stages.;
参考文献
Chemical Communications, , # 18 p. 1855 - 1857
反应条件
formic acid T=101°C;
参考文献
Chemical Communications, , vol. 46, # 10 p. 1640 - 1642
反应条件
n-butyllithium 1.) Et2O, -78 deg C 2.) r. t., 0.5 h; Yield given. Multistep reaction;
参考文献
Journal of the Chemical Society, Perkin Transactions 2: Physical Organic Chemistry (1972-1999), , # 1 p. 137 - 146
反应条件
in benzene-d6 stirred for a few min, left standing in NMR tube at 22°C for several h; reversible reaction; not isolated; (1)H NMR spectral data;
参考文献
Tang, Hui
Organometallics, 2000 , vol. 19, # 23 p. 4810 - 4819
反应条件
in chloroform-d1 in an NMR tube, 7 days at room temp. (50 percent conversion), after 24 h heating at 75 .degre.C the reaction was complete; detected by NMR;
参考文献
Journal of Organometallic Chemistry, , vol. 600, # 1-2 p. 71 - 83
反应条件
in chloroform-d1 in an NMR tube, over 14 days at room temp. and after heating at 75 .degre.C for other 14 days; detected by NMR;
参考文献
Journal of Organometallic Chemistry, , vol. 600, # 1-2 p. 71 - 83
反应条件
in chloroform-d1 in an NMR tube, 7 days at room temp. (50 percent conversion), after 24 h heating at 75 .degre.C the reaction was complete; detected by NMR;
参考文献
Journal of Organometallic Chemistry, , vol. 600, # 1-2 p. 71 - 83
反应条件
in chloroform-d1 in an NMR tube, over 14 days at room temp. and after heating at 75 .degre.C for other 14 days; detected by NMR;
参考文献
Journal of Organometallic Chemistry, , vol. 600, # 1-2 p. 71 - 83
