1-氯-2,4-二硝基苯合成路线 （共 755 条）
反应条件
1: 1H-imidazole With sodium hydride in dimethyl sulfoxide; mineral oil T=20°C; 0.5 h; 2: 1-chloro-2,4-dinitro-benzene With copper(l) iodide in dimethyl sulfoxide; mineral oil T=120°C; 24 h; Enzymatic reaction;
参考文献
Yang, Qichao; Wang, Yufang; Zhang, Baoji; Zhang, Mingjie
Chinese Journal of Chemistry, 2012 , vol. 30, # 10 p. 2389 - 2393,5
反应条件
1.1: t-BuOK / 1-methyl-pyrrolidin-2-one; dioxane / 20 - 70 °C 1.2: 1-methyl-pyrrolidin-2-one; dioxane / 70 °C 1.3: HCl / dioxane 2.1: Fe; AcOH / 1-methyl-pyrrolidin-2-one; dioxane / 3 h / 85 °C View Scheme
参考文献
Gallou, Fabrice; Yee, Nathan; Qiu, Fenghe; Senanayake, Chris; Linz, Guenter; Schnaubelt, Juergen; Soyka, Rainer
Synlett, 2004 , # 5 p. 883 - 885
反应条件
1: water; methanol / 0 - 30 °C 2: sodium sulfide; sodium hydrogencarbonate / water; methanol / 25 - 80 °C View Scheme
参考文献
AURIGENE DISCOVERY TECHNOLOGIES LIMITED; SENGUPTA, Saumitra; RAJAGOPALAN, Srinivasan; BELAVAGI, Ningaraddi; RAMACHANDRA, Muralidhara
Patent: WO2012/59932 A1, 2012 ;
WO 2012/059932 A1
反应条件
pyridine in methanol 3 h; Heating;
参考文献
Devi; Achaiah; Malla Reddy
Journal of the Indian Chemical Society, 1988 , vol. 65, # 8 p. 567 - 570
反应条件
sodium acetate in ethanol 2 h; Heating;
参考文献
Burlov; Ikorskii; Uraev; Koshchienko; Vasil'chenko; Garnovskii; Borodkin; Nikolaevskii
Russian Journal of General Chemistry, 2006 , vol. 76, # 8 p. 1282 - 1287
反应条件
in methanol T=65°C; 4 h; Product distributionMechanism;
参考文献
Plakidin, Val. L.; Vostrova, V. N.
Journal of Organic Chemistry USSR (English Translation), 1982 , vol. 18, p. 295 - 303
Zhurnal Organicheskoi Khimii, 1982 , vol. 18, # 2 p. 342 - 352
参考文献
Spectrochimica Acta, Part A: Molecular and Biomolecular Spectroscopy, , vol. 47, # 9 p. 1225 - 1234
反应条件
in acetonitrile Substitution; 72 h; Heating;
参考文献
Nanasawa, Masato; Miwa, Makio; Hirai, Michiko; Kuwabara, Tetsuo
Journal of Organic Chemistry, 2000 , vol. 65, # 2 p. 593 - 595
反应条件
in ethylene glycol T=120°C; 6 h; Product distribution / selectivity;
参考文献
FUJI PHOTO FILM CO., LTD.
Patent: WO2005/95342 A1, 2005 ;
Location in patent: Page/Page column 27-28 ;
反应条件
1: 65 percent / CH3ONa / methanol 2: CH3ONa / methanol / 25 °C / dependence on CH3ONa concentration View Scheme
参考文献
Machacek, Vladimir; Sterba, Vojeslav; Kolb, Ivan; Lycka, Antonin
Collection of Czechoslovak Chemical Communications, 1988 , vol. 53, # 5 p. 1044 - 1052
