甲基α-D-吡喃葡萄糖苷合成路线 （共 276 条）
反应条件
in dichloromethane T=25°C; 0.5 h;
参考文献
De Luca, Lidia; Giacomelli, Giampaolo; Porcheddu, Andrea
Journal of Organic Chemistry, 2002 , vol. 67, # 15 p. 5152 - 5155
反应条件
1: 87 percent / TsOH / dimethylformamide / 45 °C 2: 66 percent / NaH / dimethylformamide 3: 100 percent / NaH / dimethylformamide View Scheme
参考文献
RELIABLE BIOPHARMACEUTICAL CORPORATION; PATEL, Payal Parth; MA, Chun; OHRR, Kevin K.; NADJI, Sourena
Patent: WO2013/115817 A1, 2013 ;
反应条件
water T=350°C; 0.0333333 h; hydrothermolysis of several carbohydrates, various temperature; Product distribution;
参考文献
Kallury, R. Krishna M. R.; Ambidge, Chris; Tidwell, Thomas T.; Boocock, David G. B.; Agblevor, Foster A.; Stewart, Daniel J.
Carbohydrate Research, 1986 , vol. 158, p. 253 - 261
参考文献
Hibbert; Hassan
Journal of the Society of Chemical Industry, London, 1927 , vol. 46, p. 407 T, 408 T
反应条件
1: 91.2 percent / pyridine / Ambient temperature 2: 85.2 percent / NaH, Bu4NI / tetrahydrofuran / 24 h / Ambient temperature 3: 85.3 percent / conc. H2SO4 / ethanol / 3 h / Ambient temperature 4: CrO3, H2SO4 / acetone / 0.5 h / Ambient temperature 5: NaHCO3 / dimethylsulfoxide / 8 h / Ambient temperature View Scheme
参考文献
Goto, Junichi; Murao, Naoaki; Oohashi, Junji; Ikegawa, Shigeo
Steroids, 1998 , vol. 63, # 4 p. 180 - 185
反应条件
1: 87 percent / TsOH / dimethylformamide / 45 °C 2: 66 percent / NaH / dimethylformamide 3: 100 percent / NaH / dimethylformamide View Scheme
参考文献
RELIABLE BIOPHARMACEUTICAL CORPORATION; PATEL, Payal Parth; MA, Chun; OHRR, Kevin K.; NADJI, Sourena
Patent: WO2013/115817 A1, 2013 ;
反应条件
1: 80 percent sodium hydride in mineral oil / 3 h / 120 °C 2: 2 M H2SO4 / acetic acid / 24 h / 90 °C 3: 42 percent / sodium, deuterium oxide / dioxane / 72 h / Ambient temperature 4: 1.) hydrogen, glacial acetic acid, 2.) ammonium hydroxide / 1.) palladium black / 1.) 1 atm, 24 h, 2.) methanol, 2 h View Scheme
参考文献
Hardick, David J.; Hutchinson, David W.; Trew, Sally J.; Wellington, Elizabeth M. H.
Tetrahedron, 1992 , vol. 48, # 30 p. 6285 - 6296
反应条件
1: 90 percent / PTSA / dimethylformamide / 4 h / 70 °C 3: 10 percent / BaCO3, NBS / CCl4 / 1 h / Heating View Scheme
参考文献
Chen, Langqiu; Shi, Shen-De; Liu, Yong-Qing; Gao, Qing-Jiao; Yi, Xing; Liu, Kai-Ke; Liu, Hao
Carbohydrate Research, 2011 , vol. 346, # 10 p. 1250 - 1256
反应条件
1: p-toluenesulfonic acid / acetonitrile / 5 h / 20 °C 2: 10 g / aq. NaOH; tetrabutylammonium bromide / CH2Cl2 / 5 h / 20 °C View Scheme
参考文献
Mallet, Jean-Maurice; Meyer, Gilbert; Yvelin, Frederic; Jutand, Anny; Amatore, Christian; Sinay, Pierre
Carbohydrate Research, 1993 , vol. 244, # 2 p. 237 - 246
反应条件
1: camphor-10-sulfonic acid / acetonitrile / |Reflux 2: sodium hydride View Scheme
参考文献
University of Iowa Research Foundation; Kraus, George A.; Maury, Wendy
Patent: US2013/252909 A1, 2013 ;
