ethanol in hexane byproducts: ethane; Ar, ethanol in hexane added dropwise to a soln. of AlEt3 at -30°C; hexane was distilled off; residue was vac. distilled;
参考文献
Grosse; Mavity
Journal of Organic Chemistry, 1940 , vol. 5, p. 114
1: With zirconocene dichloride in dichloromethane T=20°C; Negishi carboalumination reaction; 8 h; 2: With hydrogenchloride in dichloromethane; water T=0°C;
参考文献
Journal of Molecular Catalysis A: Chemical, , vol. 321, # 1-2 p. 71 - 76
1: triethylaluminum in hexane T=20°C; 1 h; 2: 4-(tert-butyl)phenylacetylene With zirconocene dichloride in hexane T=20°C; Negishi carboalumination reaction; 8 h; 3: With hydrogenchloride in hexane; water T=0°C;
参考文献
Journal of Molecular Catalysis A: Chemical, , vol. 321, # 1-2 p. 71 - 76
1: triethylaluminum in hexane T=20°C; 1 h; 2: 4-(tert-butyl)phenylacetylene With zirconocene dichloride in hexane T=20°C; Negishi carboalumination reaction; 8 h; 3: With hydrogenchloride in hexane; water T=0°C;
参考文献
Journal of Molecular Catalysis A: Chemical, , vol. 321, # 1-2 p. 71 - 76
