1: With tantalum pentachloride in hexane
T=20°C; 7 h; Inert atmosphere;
2: With oxygen in hexane
T=5 - 8°C; 2 h;
参考文献
Sultanov, Rifkat M.; Samoilova, Elena V.; Popod'Ko, Natal'Ya R.; Tulyabaev, Artur R.; Sabirov, Denis Sh.; Dzhemilev, Usein M.
Tetrahedron Letters, 2013 , vol. 54, # 48 p. 6619 - 6623
in hexane
N2-atmosphere; addn. of 2 equiv. AlEt3 to borane (-78°C), stirring (room temp., 20 h); not isolated, reaction followed by (11)B- and (27)Al-NMR spectroscopy;
参考文献
Feulner, Herta; Metzler, Nils; Noeth, Heinrich
Journal of Organometallic Chemistry, 1995 , vol. 489, # 1-2 p. 51 - 62
in hexane
N2-atmosphere; addn. of 1 equiv. AlEt3 to borane (-78°C), stirring (room temp., 1 d); not isolated, reaction followed by (11)B- and (27)Al-NMR spectroscopy;
参考文献
Feulner, Herta; Metzler, Nils; Noeth, Heinrich
Journal of Organometallic Chemistry, 1995 , vol. 489, # 1-2 p. 51 - 62
