1: With bis(1-neomenthylindenyl)ZrCl2 in hexane T=22°C; 24 h; Inert atmosphereSchlenk technique; 2: With oxygen in hexane T=0°C; 26 h; 3: With hydrogenchloride; water in hexane T=0°C; enantioselective reaction;
参考文献
Parfenova, Lyudmila V.; Kovyazin, Pavel V.; Tyumkina, Tatyana V.; Berestova, Tatyana V.; Khalilov, Leonard M.; Dzhemilev, Usein M.
Journal of Organometallic Chemistry, 2013 , vol. 723, p. 19 - 25
1: With tantalum pentachloride in hexane T=20°C; 7 h; Inert atmosphere; 2: With oxygen in hexane T=5 - 8°C; 2 h;
参考文献
Sultanov, Rifkat M.; Samoilova, Elena V.; Popod'Ko, Natal'Ya R.; Tulyabaev, Artur R.; Sabirov, Denis Sh.; Dzhemilev, Usein M.
Tetrahedron Letters, 2013 , vol. 54, # 48 p. 6619 - 6623
iodine; methyl iodide in ethanol Sonication; N2; CH3I, I2 and Al introduced in a condenser with C2H5OH at -20°C, ultrasonic acceleration at room temp. for 2 h, Et3Al (ratio MeI/Et3Al = 1.50) dropped into soln. within 10 min, sonication for 30 min; distilled (vac.);
参考文献
Yang, Paw-Hwa; Liou, Kou-Fu; Lin, Yih-Tsung
Journal of Organometallic Chemistry, 1986 , vol. 307, p. 273 - 278
