carbon monoxide in tetrahydrofuran; hexane High Pressure; 0.05 mmol Pd compound, 0.1 mmol Et3B, 2,5 ml THF/hexane (24/1), CO 30 atm (at -50°C), stirred for 2 h at 25°C; GC-MS, GC;
参考文献
Journal of Organometallic Chemistry, , vol. 356, p. 125 - 132
sodium hydride in mineral oil reduction of PCl3 with NaH and B(C2H5)3 in mineral oil at -10-30 °C; formation of Na(BH(C2H5)3) as intermediate and reducing agent;; sukking off PH3 in vacuum;;
