hydrogenchloride; dihydrogen peroxide in water
mixt. of hot aq. suspn. of Pt-complex with 30percent aq. H2O2 and concd. HCl was heated with stirring for 10-30 min at ca. 80°C; filtered, washed with cold water, dried under vac.;
参考文献
Peloso, Arnaldo
Journal of the Chemical Society, Dalton Transactions: Inorganic Chemistry (1972-1999), 1983 , p. 1285 - 1290
tetraethylammonium chloride in acetonitrile
Kinetics; reactn. of Pt- and Au-complexes in the presence of Et4NCl at 50°C, ionic strength 0.10 mol/dm**3 (Et4NClO4); followed spectrophotometrycally;
参考文献
Peloso, Arnaldo
Journal of the Chemical Society, Dalton Transactions: Inorganic Chemistry (1972-1999), 1983 , p. 1285 - 1290
in neat (no solvent)
byproducts: NH(CH(CH3)2)2; thermal decompn. of Pt-complex at 615 and 676 K; further by-products;
参考文献
Al Takhin, Ghassan; Skinner, Henry A.; Zaki, Ahmed A.
Journal of the Chemical Society, Dalton Transactions: Inorganic Chemistry (1972-1999), 1983 , p. 2323 - 2328