oxygen in tetrahydrofuran byproducts: BO2(1-); stoich. amts. of BH(OCHMePh)2 and (OEP)Rh-H in THF were mixed and exposed to air; formation of PhCH(Me)OH was confirmed by gas chromy.;
参考文献
Journal of the American Chemical Society, , vol. 108, # 5 p. 943 - 947
1: With trichlorosilane in dichloromethane T=0°C; 0.5 h; Inert atmosphere; 2: With N-((1R,2S)-1-hydroxy-1-phenylpropan-2-yl)-N-methylpicolinamide in dichloromethane T=0°C; 72 h; Inert atmosphere; 3: With sodium hydrogencarbonate in dichloromethane; water Saturated solution; optical yield given as percent eeenantioselective reaction;
[H(OEt2)2]+[[3,5-(CF3)2C6H3]4B]-; C32H63CoNP2Si; hydrogen in tetrahydrofuran T=25°C; P=760.051 Torr; 21 h;
参考文献
Zhang, Guoqi; Scott, Brian L.; Hanson, Susan K.
Angewandte Chemie - International Edition, 2012 , vol. 51, # 48 p. 12102 - 12106
Angew. Chem., 2012 , p. 12077
