sulfuric acid in water; acetonitrile T=21°C; 1 h; Irradiationinvestigation of the selectivity of the phenethyl carbenium ion in the photoaddition of a binary aq. sol. of the corresponding alcohol; structural, nucleophilic and irradiation time effects are explored; Product distributionRate constant;
参考文献
Canadian Journal of Chemistry, , vol. 66, p. 2412 - 2421
sulfuric acid in water; acetonitrile T=21°C; 1 h; Irradiationinvestigation of the selectivity of the phenethyl carbenium ion in the photoaddition of a binary aq. sol. of the corresponding alcohol; structural and nucleophilic effects are discussed; Product distributionQuantum yieldRate constant;
参考文献
Canadian Journal of Chemistry, , vol. 66, p. 2412 - 2421
5,10,15,20-tetrakis-pentafluorophenyl-21H,23H-porphyrin iron(III) chloride; 3-chloro-benzenecarboperoxoic acid in dichloromethane T=-78°C; 0.5 h; other aromatic and aliphatic aldehydes, other iron(III) porphyrin complexes; deuterium isotope effects for the oxidation of aldehydes; Product distributionMechanism;
参考文献
Watanabe, Yoshihito; Takehira, Katsuomi; Shimizu, Masao; Hayakawa, Takashi; Orita, Hideo
Journal of the Chemical Society, Chemical Communications, 1990 , # 13 p. 927 - 928