三(三甲基硅烷基)-甲烷硫醇合成路线 （共 5 条）
反应条件
methyllithium in hexane T=-78°C;
参考文献
Ricci, Alfredo; Innocenti, Alessandro Degl'; Ancillotti, Monica; Seconi, Giancarlo; Dembech, Pasquale
Tetrahedron Letters, 1986 , vol. 27, # 49 p. 5985 - 5988
反应条件
hydrogen sulfide; silver nitrate
1.) MeOH, water, acetonitrile; 2.) CHCl3; Yield given. Multistep reaction;
参考文献
Block,E.; Aslam,M.
Journal of the American Chemical Society, 1985 , vol. 107, p. 6729
反应条件
sulfur; water; methyllithium; 2.) acid
1.) light petroleum; Yield given. Multistep reaction. Yields of byproduct given;
参考文献
Ricci, Alfredo; Degl'Innocenti, Alessandro; Fiorenza, Mariella; Dembech, Pasqualle; Ramadam, Nazmi; et al.
Tetrahedron Letters, 1985 , vol. 26, # 8 p. 1091 - 1092
反应条件
methyllithium; sulfur
1.) THF, reflux, 16 h; 2.) 25 deg C, 2 h; Yield given. Multistep reaction;
参考文献
Block, Eric; Aslam, Mohammad
Tetrahedron Letters, 1985 , vol. 26, # 19 p. 2259 - 2262
反应条件
1: 100 percent / 7 h / 230 - 240 °C
2: 85 percent / 1 M sulfuric acid / tetrahydrofuran / 0.5 h / 25 °C
View Scheme
参考文献
Block, Eric; Aslam, Mohammad
Tetrahedron Letters, 1985 , vol. 26, # 19 p. 2259 - 2262
