2-氨基-4-硝基甲苯合成路线 （共 108 条）
反应条件
N,N'-dimethyl-N,N'-di(pyridin-4-yl)ferrocene-1,1'-dicarboxamide T=20°C; 0.583333 h;
参考文献
Kashyap, Bishwapran; Phukan, Prodeep
RSC Advances, 2013 , vol. 3, # 35 p. 15327 - 15336
反应条件
1: concentrated sulfuric acid; water; NaNO2 / Diazotization 2: tin; hydrochloric acid View Scheme
参考文献
Aleksandrov,I.V.; Abraduschkin,Yu.S.
J. Gen. Chem. USSR (Engl. Transl.), 1960 , vol. 30, # 10 p. 3407 - 3412,3374 - 3379
反应条件
hydrogenchloride; tin
参考文献
Albert; Ritchie
Journal and Proceedings of the Royal Society of New South Wales, 1940 , vol. 74, p. 74,79, 373
参考文献
Noelting; Collin
Chemische Berichte, 1884 , vol. 17, p. 265
反应条件
1: ice; concentrated hydrochloric acid / mit NaNO2 diazotieren und in CuCl-Loesung giessen 2: permanganate View Scheme
参考文献
Ullmann; Wagner
Justus Liebigs Annalen der Chemie, 1907 , vol. 355, p. 366
Justus Liebigs Annalen der Chemie, 1909 , vol. 371, p. 388
参考文献
Hill, Stephen V.; Thea, Sergio; Williams, Andrew
Journal of the Chemical Society, Perkin Transactions 2: Physical Organic Chemistry (1972-1999), 1983 , p. 437 - 446
反应条件
1: glacial acetic acid; sodium nitrite / durch Diazotieren 2: alcohol; hydrogen sulfide; ammonia 3: Diazotization View Scheme
参考文献
Witt; Noelting; Grandmougin
Chemische Berichte, 1890 , vol. 23, p. 3642
Chemische Berichte, 1892 , vol. 25, p. 3152
反应条件
1: 84 percent / pyridine / CHCl3 / 6 h / 20 °C 2: 55.6 percent Turnov. / N-bromosuccinimide / CCl4 / 20 h / 20 °C / Photolysis 3: 42.2 percent / CaCO3 / dioxane; H2O / 3 h / Heating 4: 100 percent / hydrochloric acid / 16 h / 20 °C View Scheme
参考文献
Hu, Longqin; Yu, Chengzhi; Jiang, Yongying; Han, Jiye; Li, Zhuorong; Browne, Patrick; Race, Paul R.; Knox, Richard J.; Searle, Peter F.; Hyde, Eva I.
Journal of Medicinal Chemistry, 2003 , vol. 46, # 23 p. 4818 - 4821
反应条件
1: 2-Methyl-5-nitro-phenylamine With hydrogenchloride; sodium nitrite in water T=0 - 5°C; 2: With sodium tetrafluoroborate in water T=5°C; 3: 4,4,5,5-tetramethyl-1,3,2-dioxaborolan-2-yl-4',4',5',5'-tetramethyl-1,3,2-dioxaborolane With copper(I) bromide in water; acetonitrile T=20°C; Sandmeyer type reaction; 4 h;
参考文献
Zhang, Jie; Wang, Xiaolong; Yu, Haitao; Ye, Jiahai
Synlett, 2012 , vol. 23, # 9 p. 1394 - 1396
反应条件
Diazotierung und Verkochen mit Alkohol.Diazotization;
参考文献
Wassmundt, Frederick W.; Kiesman, William F.
Journal of Organic Chemistry, 1995 , vol. 60, # 6 p. 1713 - 1719
