1-邻叔丁基二甲基甲硅烷基-2-叠氮基-2-脱氧-β-D-吡喃葡萄糖苷合成路线 （共 6 条）
反应条件
nitrogen; ammonia in tetrahydrofuran; methanol; dichloromethane
参考文献
Seeberger, Peter H.; Orgueira, Hernan; Schell, Peter
Patent: US2003/13862 A1, 2003 ;
反应条件
1H-imidazole in N,N-dimethyl-formamide
6 h; Ambient temperature;
参考文献
Kinzy, Willy; Schmidt, Richard R.
Liebigs Annalen der Chemie, 1985 , # 8 p. 1537 - 1545
反应条件
1: NH3 / tetrahydrofuran; methanol / 0.25 h
2: 29.8 g / imidazole / CH2Cl2 / 2 h
View Scheme
参考文献
Orgueira, Hernan A.; Bartolozzi, Alessandra; Schell, Peter; Litjens, Remy E. J. N.; Palmacci, Emma R.; Seeberger, Peter H.
Chemistry - A European Journal, 2003 , vol. 9, # 1 p. 140 - 169
反应条件
1H-imidazole in dichloromethane
2 h;
参考文献
Orgueira, Hernan A.; Bartolozzi, Alessandra; Schell, Peter; Litjens, Remy E. J. N.; Palmacci, Emma R.; Seeberger, Peter H.
Chemistry - A European Journal, 2003 , vol. 9, # 1 p. 140 - 169
反应条件
1: aq. sodium nitrite / dioxane / 8 h / 80 °C
2: 52 percent / imidazol / dimethylformamide / 6 h / Ambient temperature
View Scheme
参考文献
Kinzy, Willy; Schmidt, Richard R.
Liebigs Annalen der Chemie, 1985 , # 8 p. 1537 - 1545
反应条件
1: NaN3, cer(III)-ammonium nitrate / acetonitrile / 1.) 6 h, -30 deg C, 2.) 14 h, -25 deg C, 3.) 8 h, -15 deg C
2: aq. sodium nitrite / dioxane / 8 h / 80 °C
3: 52 percent / imidazol / dimethylformamide / 6 h / Ambient temperature
View Scheme
参考文献
Kinzy, Willy; Schmidt, Richard R.
Liebigs Annalen der Chemie, 1985 , # 8 p. 1537 - 1545
