methanol in methanol
byproducts: Me3SiCl, Me3SiOMe, Me3SiOSiMe3; a mixt. of Me3SiSnMe3 and Me2SiCl2 in methanol was kept for several days, reaction was followed by (1)H NMR spectroscopy; all of the substrate had been consumed; not isolated, identified by (1)H NMR spectrum;
参考文献
Cuthberston, Matthew J.; Wells, Peter R.
Journal of Organometallic Chemistry, 1985 , vol. 287, p. 25 - 38
in N,N,N',N',N'',N''-hexamethylphosphoric triamide
byproducts: Me3SiGeEt2H; Mixt. of Me3SiGeEt2(H) and Et3GeLi in HMPA is stirred for 72 h at 25°C.;
参考文献
Pigarev, S. D.; Bravo-Zhivotovskii, D. A.; Kalikhman, I. D.; Vyazankin, N. S.; Voronkov, M. G.
Journal of Organometallic Chemistry, 1989 , vol. 369, p. 29 - 42
methanol in methanol
Kinetics; byproducts: Me3SiCl, Me3SiOSiMe3; a mixt. of Me3SiSnMe3 and Me2SiCl2 in methanol was kept for 150 min, reaction was followed by (1)H NMR spectroscopy; 70percent of the substrate had been consumed, rate const. is given; not isolated, identified by (1)H NMR spectrum;
参考文献
Cuthberston, Matthew J.; Wells, Peter R.
Journal of Organometallic Chemistry, 1985 , vol. 287, p. 25 - 38
→
反应条件
in benzene-d6
inert atmosphere; 60°C, 10 min; not isolated, reaction followed by NMR spectroscopy;
参考文献
Hays, Mary K.; Eisenberg, Richard
Inorganic Chemistry, 1991 , vol. 30 - 12, p. 2623 - 2630
