in solid matrix
Irradiation (UV/VIS); metal was deposited into methane-doped Ar-matrix (5percent CH4) on cold (12 K)CsI window, metal:Ar ratio was 1:600; hydride was formed during irradn. at 200-400 nm for 10 min; it was decomposed during irradn. at 200-800 n m irradn. for 10 min; detected by IR and UV;
参考文献
Himmel, Hans-Joerg; Downs, Anthony J.; Greene, Tim M.; Andrews, Lester
Organometallics, 2000 , vol. 19, # 6 p. 1060 - 1070
in not given
byproducts: H2; dimethylgallane was heated at 70°C;
参考文献
Baxter, Paul L.; Downs, Anthony J.; Goode, Michael J.; Rankin, David W. H.; Robertson, Heather E.
Journal of the Chemical Society, Chemical Communications, 1986 , # 10 p. 805 - 806