trichlorophosphate T=22°C; 24 h;

in diphenylether 0.416667 h; Heating;

1: 1) nBuLi, N,N,N',N'tetramethylethylenediamine; 2) trimethylsilylmethyl azide / 1) ether, hexane, 22 degC, 18.5 h.; 2) ether, hexane, 22 degC, 3.5 h. 2: 1) MeOH, 22 degC, 4 d.; 2) diphenyl ether, reflux, 25 min. View Scheme

1: 73 percent / methanol / 72 h / 22 °C 2: 91 percent / diphenyl ether / 0.42 h / Heating View Scheme

1) MeOH, 22 degC, 4 d.; 2) diphenyl ether, reflux, 25 min.; Yield given. Multistep reaction;

1: 86 percent / POCl3 / 24 h / 22 °C 2: 61 percent / NH3 / various solvent(s) / 2 h / 180 °C View Scheme