1: With 1,10-phenanthroline; iron (III) acetylacetonate; 1,2-dichloro-2-methylpropane in tetrahydrofuran T=0°C; 1 h; Inert atmosphereSchlenk technique; 2: With hydrogenchloride in tetrahydrofuran; water Catalytic behavior; Reagent/catalyst;
1: With 1,10-phenanthroline; iron (III) acetylacetonate; 1,2-dichloro-2-methylpropane in tetrahydrofuran T=0°C; 1 h; Inert atmosphereSchlenk technique; 2: With hydrogenchloride in tetrahydrofuran; water
1: With 1,10-phenanthroline; iron (III) acetylacetonate; 1,2-dichloro-2-methylpropane in tetrahydrofuran T=0°C; 1 h; Inert atmosphereSchlenk technique; 2: With hydrogenchloride in tetrahydrofuran; water Catalytic behavior; Reagent/catalyst;
1: With N,N,N',N,-tetramethylethylenediamine in toluene T=50°C; 10 h; Inert atmosphere; 2: With water; ammonium chloride in toluene 12 h; SolventReagent/catalystTemperature;
参考文献
Zhuo, Fang-Fang; Xie, Wen-Wen; Yang, Yong-Xin; Zhang, Lei; Wang, Pei; Yuan, Rui; Da, Chao-Shan
Journal of Organic Chemistry, 2013 , vol. 78, # 7 p. 3243 - 3249
1.1: diethyl ether / 0 - 20 °C / Cooling with ice 2.1: sodium azide; sulfuric acid / chloroform / 0.5 h / Cooling with ice 2.2: 2.5 h / 20 °C 3.1: C32H35F3N2O5RuS2 / methanol / 0.08 h / 20 °C / Autoclave View Scheme
参考文献
Wang, Tianli; Zhuo, Lian-Gang; Li, Zhiwei; Chen, Fei; Ding, Ziyuan; He, Yanmei; Fan, Qing-Hua; Xiang, Junfeng; Yu, Zhi-Xiang; Chan, Albert S. C.
Journal of the American Chemical Society, 2011 , vol. 133, # 25 p. 9878 - 9891
