alpha,alpha'-二甲基二苄基胺合成路线 （共 27 条）
反应条件
N,N'-dimethyl-(R)-1,1'-binaphthyldiamine-bis-2-pyridinecarboxyamide; trichlorosilane in dichloromethane T=0°C; 12 h; Inert atmosphere; optical yield given as percent dediastereoselective reaction;
参考文献
Gulzzettl, Stefania; Benagila, Maurizio; Rossi, Sergio
Organic Letters, 2009 , vol. 11, # 13 p. 2928 - 2931
反应条件
hydrogen; palladium on activated charcoal in tetrahydrofuran P=2280 Torr; 16 h;
参考文献
Eleveld, M.B.; Hogeveen, H.; Schudde, E.P.
Journal of Organic Chemistry, 1986 , vol. 51, # 19 p. 3635 - 3642
反应条件
hydrogen; palladium on activated charcoal
参考文献
Reetz, Manfred T.; Bondarev, Oleg
Angewandte Chemie - International Edition, 2007 , vol. 46, # 24 p. 4523 - 4526
反应条件
di-tert-butyl peroxide; [IndBox]Cu T=80°C; 24 h;
参考文献
Georgetown University
Patent: US2011/213146 A1, 2011 ;
Location in patent: Page/Page column 3; 27 ;
反应条件
1: p-toluenesulfonic acid / toluene / Heating 2: H2 / Pd/C / tetrahydrofuran / 760 Torr View Scheme
参考文献
Uccello-Barretta; Bernardini; Balzano; Salvadori
Journal of Organic Chemistry, 2001 , vol. 66, # 1 p. 123 - 129
反应条件
1: p-toluenesulfonic acid / toluene / Heating 2: H2 / Pd/C / tetrahydrofuran / 760 Torr View Scheme
参考文献
Uccello-Barretta; Bernardini; Balzano; Salvadori
Journal of Organic Chemistry, 2001 , vol. 66, # 1 p. 123 - 129
反应条件
1: 51 percent / p-toluenesulfonic acid / benzene / Heating 2: hydrogen / 15percent palladium on charcoal View Scheme
参考文献
Murahashi; Yoshimura; Tsumiyama; Kojima
Journal of the American Chemical Society, 1983 , vol. 105, # 15 p. 5002 - 5011
反应条件
1: sec-phenethyl alcohol With 2,2,6,6-tetramethyl-piperidine-N-oxyl; [bis(acetoxy)iodo]benzene in dichloromethane T=20°C; 16 h; 2: (S)-1-phenyl-ethylamine With sodium tris(acetoxy)borohydride in dichloromethane optical yield given as percent dechemoselective reaction;
参考文献
Guerin, Claire; Bellosta, Veronique; Guillamot, Gerard; Cossy, Janine
Organic Letters, 2011 , vol. 13, # 13 p. 3534 - 3537
反应条件
hydrogen in isopropanol acetate T=35°C; P=15001.5 Torr; 24 h; optical yield given as percent dediastereoselective reaction;
参考文献
Nugent, Thomas C.; Negru, Daniela E.; El-Shazly, Mohamed; Hu, Dan; Sadiq, Abdul; Bibi, Ahtaram; Umar, M. Naveed
Advanced Synthesis and Catalysis, 2011 , vol. 353, # 11-12 p. 2085 - 2092
反应条件
Li[H3BN(i-Pr)2] in tetrahydrofuran T=0°C; 1 h; Yield given. Yields of byproduct given;
参考文献
Kanai, Masatomi; Ueda, Koji; Yasumoto, Manabu; Kuriyama, Yokusu; Inomiya, Kenjin; Ootsuka, Takashi; Katsuhara, Yutaka; Higashiyama, Kimio; Ishii, Akihiro
Journal of Fluorine Chemistry, 2005 , vol. 126, # 3 p. 385 - 391
