in gas
Irradiation (UV/VIS); photoreact. mixt. NO and N2/O2 with 146 nm Kr2 (25mW/cm2) excimer lamp for 30 min under atm. pressure; monitoring by IR spectrometry;
参考文献
Tsuji, Masaharu; Kamo, Naohiro; Kawahara, Takashi; Kawahara, Masashi; Senda, Makoto; Hishinuma, Nobuyuki
Bulletin of the Chemical Society of Japan, 2009 , vol. 82, # 2 p. 277 - 284
silica gel in water
Kinetics; byproducts: OH(1-), N2; Irradiation (UV/VIS); irradiation of N2O-satd. soln. containing Ru- and N3-salts and colloidalsilica at 23°C using L-band linear accelerator to a dose pf 32 G y; spectrophorometric monitoring at 310 and 450 nm;
参考文献
Naik, Devidas B.; Schnabel, Wolfram
Berichte der Bunsen-Gesellschaft, 1995 , vol. 99, # 12 p. 1559 - 1562
in gas
Irradiation (UV/VIS); mixt. of CHBr3 and N2O dild. in large excess of Ar; ca. 20 Torr total pressure; CH radicals generated by the laser-photolysis (266 nm) reacted with N2O;
in neat (no solvent, gas phase)
react. in laminar premixed flames stabilized at 5.3 kPa; gas mixt. flow:CH4 0.322-0.480 slpm (standard liters per minute), O2 0.768-0.955 slpm, N2 2.312-3.345 slpm; not isolated; detd. by fluorescence spectroscopy;
参考文献
Lamoureux, Nathalie; Mercier, Xavier; Pauwels, Jean-Francois; Desgroux, Pascale
Journal of Physical Chemistry A, 2011 , vol. 115, # 21 p. 5346 - 5353
Dillard, J. G.; Franklin, J. L.; Seitz, W. A.
Journal of Chemical Physics, 1968 , vol. 48, p. 3828 - 3829
Show Details
Gmelin Handbook: C: MVol.D1, 32.1, page 316 - 316
catalyst: manganese-bismuth oxide/α-Al2O3 in neat (no solvent)
fresh catalyst placed in a flowthrough quartz reactor; catalyst heated at various temperatures; NH3 and O2 passed through the catalyst; not isolated; detected by mass spectrometry;
