in carbon disulfide; tetrachloromethane byproducts: S7Cl2, S8Cl2, S9Cl2; dropwise addn. of a 4percent Cl2-soln. (0.094mol) in CCl4 to a soln. of 0.469mol S6 in CS2 at 0°C within 30min; warming to room temp.; furtherbyproducts;; concn. after 60min by evapn. at 20°C; filtration; removal of solvent; cooling at -35°C for several days; the viscous liquid was pipetted off from ppt. in the cold; mixt. obtained;;
参考文献
Zeitschrift fuer Naturforschung, Teil B: Anorganische Chemie, Organische Chemie, , vol. 41, # 8 p. 958 - 970
reaction of WCl2 with S under a vacuum at 350°C for 3 d; removal of the S2Cl2 byproduct by condensation, removal of excess S by heating under a dynamic vacuum; elem. anal.;
参考文献
Journal of Alloys and Compounds, , vol. 182, # 2 p. 253 - 264
