in neat (no solvent, solid phase) byproducts: H2O; Schlenk techniques; heating Eu compd. under vacuum (1E-3 Torr);
参考文献
Boyle, Timothy J.; Ottley, Leigh Anna M.; Alam, Todd M.; Rodriguez, Mark A.; Yang, Pin; Mcintyre, Sarah K.
Polyhedron, 2010 , vol. 29, # 7 p. 1784 - 1795
→
反应条件
in neat (no solvent) Al2Cl6 prepd. from Al and Cl2; in Duran tube, at 400°C (Cl2); chemical vapour phase transport with Al2Cl6 from 400 to 310°C, 24 h;
参考文献
Gunsilius, H.; Urland, W.; Kremer, R.
Zeitschrift fuer Anorganische und Allgemeine Chemie, 1987 , vol. 550, p. 35 - 40
potassium chloride; sodium acetate; acetic acid in water Kinetics; cation exchange react. at 20°C at ionic strenght 0.5 M (which was adjusted with KCl); react. was followed by polarography;
in neat (no solvent) absence of moisture; large excess AlCl3, evacuated quartz tube, 573 K; fractional sublimation over 450 to 650 K gradient, removal of residual AlCl3 on heating in Cl2/N2 stream;
