potassium hydroxide in not given byproducts: KCl, hypochlorite; slow react. in coldness; react. accelerated at higher temp.; formation of POCl3 and a dark yellow gas, forming with KOH soln. KCl, KClO3 and hypochlorite;;
参考文献
Liebigs Annalen der Chemie, , vol. 106, p. 116 - 118
in hexane Ar atmosphere, addn. of PCl5 in hexane to B-compound (during 3 h, 60-70°C), stirring (65°C, 3 h); solvent and POCl3 removal (12 Torr, 60°C); elem. anal.;
in neat (no solvent) KClO3 is covered with POCl3 layer, PCl3 is added slowly, absence of H2O is necessary otherwise formed Cl-oxides react explosively with PCl3;; PCl3 is removed via addition of ClO3(1-) when distilling;;
