sodium tetrahydroborate in ethanol High Pressure; SbCl3, cetyltrimethylammonium bromide, NaBH4 and ethanol added to a flask; mixture stirred for 30 min and then tranferred to a Teflon-lined autoclave; autoclave kept at 150°C for 30 h and then cooled to room temp. on standing; samples in the autoclave separated into two layers; the two layer samples collected, washed with distilled water and absolute alcohol for several times, and then dried at 80°C for 8 h;
Fisher
Annalen der Physik (Weinheim, Germany), 1826 , vol. 8, p. 499
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Fisher
Annalen der Physik (Weinheim, Germany), 1827 , vol. 9, p. 264
NaBH4 in tetrahydrofuran; dimethyl sulfoxide byproducts: NaCl, BH3, hydrogen; (Ar); reflux of Zn and NaBH4 in THF under stirring for 0.5 h, quick injecting of soln. of SbCl3 in THF, reflux at 75°C for 24 h, addn. ofDMSO; heating at 190°C;
参考文献
Denoix; Solaiappan; Ayral; Rouessac; Tedenac
Journal of Solid State Chemistry, 2010 , vol. 183, # 5 p. 1090 - 1094
