in diethylene glycol dimethyl ether SiCl4 was reacted with LiAlD4 in diglyme; fractionally condensed in vac.;
参考文献
Bihlmeier, Angela; Greene, Tim M.; Himmel, Hans-Joerg
Organometallics, 2004 , vol. 23, # 10 p. 2350 - 2361
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反应条件
in not given
参考文献
Arthur, Neville L.; Potzinger, Peter; Reimann, Bruno; Steenbergen, H. Peter
Journal of the Chemical Society, Faraday Transactions 2: Molecular and Chemical Physics, 1989 , vol. 85, p. 1447 - 1464
in neat (no solvent) under inert atmosphere; eqimolar amt. of SiCl4 and SiBr4 equilibrated by stirring at room temp. for 3 d; sepd. by repeated fractional distn. at ambient pressure; immediately frozen; characterized by (29)Si NMR;
参考文献
Hcnsen, Karl; Mayr-Stein, Ralf; Stumpf, Thorsten; Pickel, Peter; Boite, Michael; Fleischer, Holger
Journal of the Chemical Society, Dalton Transactions, 2000 , # 4 p. 473 - 477
in gas High Pressure; reagents added to tube in dry ice bath, sealed in amts. to develop about 30-50 atm of pressure at 300°C, heated at 310-350°C for 1.5-69 h; analyzed by GLC;
参考文献
Scaduto, Patricia M.; Speier, John L.
Inorganic Chemistry, 1983 , vol. 22, p. 3363 - 3364
in gas High Pressure; reagents added to tube in dry ice bath, sealed in amts. to develop about 30-50 atm of pressure at 300°C, heated at 350°C for 65 h; analyzed by GLC;
参考文献
Scaduto, Patricia M.; Speier, John L.
Inorganic Chemistry, 1983 , vol. 22, p. 3363 - 3364
in neat (no solvent) quiet electric discharges on a H2 stream with the mixture of SiCl4- and Br2-vapors, passed through a discharge tube;; mixture obtained;;
in neat (no solvent) form of SiCl4 and molten KI;;
参考文献
Forbes, G. S.; Anderson, H. H.
Journal of the American Chemical Society, 1944 , vol. 66, p. 931 - 933
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Gmelin Handbook: Si: MVol.B, 275, page 742 - 743
