in further solvent(s)
heating a suspension of PO(OH)2NH2 in tetrachlorethane with PCl4 on refluxing under exclusion of H2O for 4 h;; filtration of insol. products; continous removal of HCl with stream of dry air; expelling POCl3 and solvent at 90 °C and 14 Torr; solidification in high vac. at 55-58 °C;;
参考文献
Becke-Goehring, M.; Mann, T.; Euler, H. D.
Chemische Berichte, 1961 , vol. 94, p. 193 - 198
metal(I) chloride in further solvent(s)
byproducts: metal(I) phosphorus hexaflouride; react. of metal chloride MCl with PCl5 in liquid HF forming HCl and MPF6;;
参考文献
Woyski, M. M.
Audrieth, L. F., Inorganic Syntheses, Bd. 3, New York-Toronto-London 1950, S. 111
