in neat (no solvent)
byproducts: (NPCl2)3, (NPCl2)4; heating NH4Cl with PCl5 in an autoclave with glass charge at 170 °C for 2-3 days; repeated exhausting of formed gaseous HCl; removal of (NPCl2)3 and (NPCl2)4 with hot petroleum ether; removal of (NPCl2)(n) on distg. at 360 °C in vac.;; distn. of the oily brown residue at 400 °C in high vac.; extraction of the oil with boiling petroleum ether to remove lower homologues; boiling the soln. in C6H6 with dry active coal; filtration and removal of the solvent at reduced pressure;;
参考文献
Becke-Goehring, M.; Koch, G.
Ch.-Ber., 1959 , vol. 92, p. 1188 - 1195
in neat (no solvent)
heating with SO2(NH2)2 at 90 °C;; quantitative react.;;
参考文献
Kirsanov, A. V.
Zh. obshch. Khim., 1952 , vol. 22, p. 1346 - 1349
C., 1956 , p. 1242
Full Text Show Details
Gmelin Handbook: P: MVol.C, 192, page 441 - 443
in neat (no solvent)
ratio (HSO3Cl/PCl5) 1:1; decompn. of S2O5Cl2;;
参考文献
Michaelis, A.
Jena. Z. Med. Naturwiss., 1873 , vol. 7, p. 110 - 117
Full Text Show Details
Michaelis, A.
Jena. Z. Med. Naturwiss., 1870 , vol. 6, p. 235 - 238
Geuther, A.
Jena. Z. Med. Naturwiss., 1873 , vol. 7, p. 380 - 390
Full Text Show Details
Geuther, A.
J. prakt. Chem. (2), 1874 , vol. 8, p. 359 - 372
Full Text Show Details
Gmelin Handbook: P: MVol.C, 193, page 443 - 445
in water
no Cl2 or other Cl-containing compd. is formed;;
参考文献
Spring
Bulletin de la Classe des Sciences, Academie Royale de Belgique, 1875 , vol. 39, p. 905 - 905
Full Text Show Details
Gmelin Handbook: Cl: MVol., 143, page 387 - 388
