in further solvent(s)
NH4Cl reacted with PCl5 in 1,1,2,2-tetrachloroethane according to L. G. Lund, N. L. Paddock, J. E. Proctor, H. T. Searle, Journal of the Chemical Society (1960) 2542; vac. distilled on Vigreux column;
参考文献
Vorontsov, Ivan I.; Tur, Dzidra R.; Papkov, Vladimir S.; Antipin, Mikhail Yu.
Journal of Molecular Structure, 2009 , vol. 928, # 1-3 p. 1 - 11
in not given
react. with an equimolar amount of H(B(OH)2F2); evolution of HCl starting in coldness, complete removal of HCl on heating;;
参考文献
Long, L. H.; Dollimore, D.
Journal of the Chemical Society, 1951 , p. 1608 - 1612
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Gmelin Handbook: P: MVol.C, 193, page 443 - 445
in neat (no solvent)
heating with amidosulfuric acid at 100 °C; formation of POCl3 and HCl in the distillate and ClSO2NPCl3 containing only traces of Cl2 as residue;;
参考文献
Kirsanov, A. V.
Zh. obshch. Khim., 1952 , vol. 22, p. 88 - 93
C. A., 1952 , p. 6984
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Gmelin Handbook: P: MVol.C, 192, page 441 - 443
in not given
react. of an excess of PCl5 with OP(NH2)3 without removal of formed HCl; primary formation of OP(NH2)2Cl, condensation forming ((NH)2(POCl2)2)(n); further react. with PCl5 forming POCl3, NH3 and (PNCl2)(n);;
参考文献
Becke-Goehring, M.; Mann, T.; Euler, H. D.
Chemische Berichte, 1961 , vol. 94, p. 193 - 198
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Gmelin Handbook: P: MVol.C, 192, page 441 - 443
in not given
react. of PCl5 with OP(NH2)3 without removal of formed HCl; primary formation of OP(NH2)2Cl, condensation forming ((NH)2(POCl2)2)(n); further react. with PCl5 forming POCl3, NH3 and (PNCl2)(n);;
参考文献
Becke-Goehring, M.; Mann, T.; Euler, H. D.
Chemische Berichte, 1961 , vol. 94, p. 193 - 198
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Gmelin Handbook: P: MVol.C, 192, page 441 - 443
Kirsanov, A. V.
Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, 1954 , p. 551 - 558
Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, 1954 , p. 646 - 655
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Gmelin Handbook: C: MVol.D1, 45.8.4.8, page 423 - 423
in further solvent(s)
(argon); refluxing PCl5 and (NH4)2SO4 1 h in tetrachloroethane, removal of volatiles (vac.), after cooling addn. of SO2; filtration, removal of solvent (vac.), purifn. by microdistn.;
参考文献
Stock; Schnick
Zeitschrift fur Naturforschung - Section B Journal of Chemical Sciences, 1996 , vol. 51, # 8 p. 1079 - 1083
