in trichlorophosphate mixing solutions of PCl5 and CrO2Cl2 in POCl3; pptn. of a ppt. with composition PCl5*CrO2Cl2;;
参考文献
Nisel'son, L. A.; Tret'yakova, K. V.; Kireev, S. M.; Drobot, D. B.
Russian Journal of Inorganic Chemistry (Translation of Zhurnal Neorganicheskoi Khimii), 1982 , vol. 27, p. 497 - 499
Zhurnal Neorganicheskoi Khimii, 1982 , vol. 27, p. 887 - 890
in neat (no solvent) heating with Mg3(PO4)2 in a sealing tube; formation of an adduct of react. products with POCl3, evolution of POCl3 on heating at higher temp.;;
参考文献
Buchanan, J. Y.
Ber., 1870 , vol. 3, p. 485 - 486
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Gmelin Handbook: P: MVol.C, 200, page 458 - 460
Ehrenfeld, C. H.
Journal of the American Chemical Society, 1895 , vol. 17, p. 381
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Gmelin Handbook: W: MVol., 2.3.2.2, page 123 - 127
exothermic react.; removing C4H9Cl and OPCl3 at reduced pressure, distn. of residue;
参考文献
Mikhailov, B. M.; Shchegoleva, T. A.
Bull. Acad. Sci. USSR Div. Chem. Sci., 1956 , p. 501 - 502
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Gmelin Handbook: B: B-Verb.9, 6.2.3, page 280 - 286