ammonia; oxygen in water
byproducts: H2O2; in dild. aq. soln. of NH3;
参考文献
Carius, L.
Ber., 1874 , vol. 7, p. 1481
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Carius, L.
Liebigs Annalen der Chemie, 1874 , vol. 174, p. 51
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Gmelin Handbook: NH4: MVol.1, 1.5, page 12 - 20
in neat (no solvent)
reaction by use of NH3 in exceed;;
参考文献
Helmholtz, R. v.; Richarz, F.
Annalen der Physik (Weinheim, Germany), 1890 , vol. 40, p. 161 - 202
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Gmelin Handbook: O: MVol.4, 79, page 1157 - 1160
→
反应条件
in water
reaction by introducing of O3 in aq. (NH4)2SO4 soln.;; detection: distinct reaction to nitrate, but slight reaction to nitrite only;;
参考文献
Gmelin Handbook: O: MVol.4, 89, page 1178 - 1180
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Dieckhoff, E.
Habilitationsschr. Karlsruhe T. H. 1891, S. 61
oxygen in neat (no solvent)
passing ozonized O2 over pure P2O3 at 25°C and 1 atm there is oxidation without luminescence, ratio crystalline products P4O8 and P4O10 5:3 with consumption of 1 Mol O3 per 4 Mol P2O3;;
参考文献
Miller, C. C.
Journal of the Chemical Society, 1929 , p. 1829 - 1846
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Gmelin Handbook: P: MVol.C, 36, page 72 - 73
phosphoric acid; oxygen in not given
reaction by introducing of a gaseous O3-O2 mixture into KI-containing phosphate buffer solns. (pH value of 6.8), reaction mechanism discussed;;
参考文献
Gueron, G.; Prettre, M.; Gueron, J.
Bulletin de la Societe Chimique de France, 1936 , vol. 3, p. 1841 - 1847
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Gmelin Handbook: O: MVol.4, 88, page 1176 - 1178
Na2CO3 or K2CO3 in not given
reaction by use of a O3-O2 mixture in a Na2CO3- or K2CO3-containing alcaline 0.1n-KI soln. for a period of 20-30 min.;;
参考文献
Willard, H. H.; Merritt, L. L.
Industrial and Engineering Chemistry, Analytical Edition, 1942 , vol. 14, p. 489 - 490
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Gmelin Handbook: O: MVol.4, 88, page 1176 - 1178
Carius, L.
Ber., 1872 , vol. 5, p. 520 - 526
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Carius, L.
Liebigs Annalen der Chemie, 1874 , vol. 174, p. 1 - 30
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Gmelin Handbook: O: MVol.4, 85, page 1170 - 1172
